2-MeTHF has solvating properties that are intermediate between diethyl ether and THF, has limited water miscibility, and forms an azeotrope with water on distillation. Its lower melting point makes it useful for lower temperature reactions, and its higher boiling point allows procedures under reflux at higher temperatures (relative to THF).
|
|
DMI has excellent solvating ability for both inorganic and organic compounds. In many applications, DMI (as well as DMPU) can be used as a substitute or replacement for the carcinogenic solvent HMPA. DMI is used in a variety of applications including detergents, dyestuffs, electronic materials and in the manufacture of polymers. DMI is toxic in contact with skin.
|
|
Solvents such as water can both donate and accept hydrogen bonds, making them excellent at solvating solutes that can donate or accept (or both) H-bonds. Some chemical compounds experience solvatochromism, which is a change in color due to solvent polarity. This phenomenon illustrates how different solvents interact differently with the same solute. Other solvent effects include conformational or isomeric preferences and changes in the acidity of a solute.
|
|
Supercritical carbon dioxide (SCD) can be used instead of PERC (perchloroethylene) or other undesirable solvents for dry-cleaning. Supercritical carbon dioxide sometimes intercalates into buttons, and, when the SCD is depressurized, the buttons pop, or break apart. Detergents that are soluble in carbon dioxide improve the solvating power of the solvent. CO2-based dry cleaning equipment uses liquid CO2, not supercritical CO2, to avoid damage to the buttons.
|
|
Gold(I) complexes can polymerize by intermolecular aurophilic interaction. Nanoparticles that form from this polymerization often give rise to intense luminescence in the visible region of the spectrum. Strength of particular intermolecular aurophilic interactions can be gauged by solvating the nanoparticles and observing the extent to which luminescence diminishes. The similarity in strength between hydrogen bonding and aurophilic interaction has proven to be a convenient tool in the field of polymer chemistry.
|
|
Ionic liquids are often moderate to poor conductors of electricity, non- ionizing, highly viscous and frequently exhibit low vapor pressure. Their other properties are diverse: many have low combustibility, are thermally stable, with wide liquid regions, and favorable solvating properties for a range of polar and non-polar compounds. Many classes of chemical reactions, such as Diels-Alder reactions and Friedel-Crafts reactions, can be performed using ionic liquids as solvents. ILs can serve as solvents for biocatalysis.
|
|
CDAs are used with NMR spectroscopic analysis to determine enantiomeric excess and the absolute configuration of a substrate. Chiral discriminating agents are sometimes difficult to distinguish from chiral solvating agents (CSA) and some agents can be used as both. The speed of the exchange between the substrate and the metal center is the most important determining factor to differentiate between the use of a compound as a CDA or CSA. Generally, a CDA has a slow exchange whereas a CSA has a fast exchange.
|
|
Sodium ethoxide is commonly used as a base in the Claisen condensation and malonic ester synthesis. Sodium ethoxide may either deprotonate the α-position of an ester molecule, forming an enolate, or the ester molecule may undergo a nucleophilic substitution called transesterification. If the starting material is an ethyl ester, trans- esterification is irrelevant since the product is identical to the starting material. In practice, the alcohol/alkoxide solvating mixture must match the alkoxy components of the reacting esters to minimize the number of different products.
|
|
In this case, W = -10.39 kcal/mol. In other cases, W is the enthalpy needed to cleave the internal hydrogen bonding of the H-bonding acid (CF3)3COH. W is also useful for a base displacement reaction in poorly solvating media: :F3B-OEt2 → BF3 \+ OEt2 For any base, a constant energy contribution is observed for the breaking of the F3B-OEt2 bond. An ECW study of the enthalpies of a series of bases produces a W value that corresponds to the enthalpy of dissociation of the F3B-OEt2 bond.
|
|
The batteries are made in Bolloré owned facilities in two locations, one in Brittany, France and the other in Montreal, Quebec, Canada. Bolloré is unique in integrating solid- state batteries into production vehicles. The LMP batteries consist of a laminate of four ultra-thin materials: (1) metallic lithium foil anode that acts as both a lithium source and a current collector; (2) solid polymeric electrolyte created by dissolving a lithium salt in a solvating co-polymer (polyoxyethylene); (3) cathode composed of vanadium oxide, carbon, and polymer to form a plastic composite; and (4) aluminium foil current collector.
|
|
The fluorinase catalyses an SN2-type nucleophilic substitution at the C-5' position of SAM, while L-methionine acts as a neutral leaving group. The fluorinase-catalysed reaction is estimated to be between 106 to 1015 times faster than the uncatalysed reaction, a significant rate enhancement. Despite this, the fluorinase is still regarded as a slow enzyme, with a turnover number (kcat) of 0.06 min−1. The high kinetic barrier to reaction is attributed to the strong solvation of fluoride ion in water, resulting in a high activation energy associated with stripping solvating water molecules from aqueous fluoride ion, converting fluoride into a potent nucleophile within the active site.
|
|
The draw back such models is that they can lack physical insight. A method founded in physical theory, capable of achieving similar levels of accuracy at an sensible cost, would be a powerful tool scientifically and industrially. Methods founded in physical theory tend to use thermodynamic cycles, a concept from classical thermodynamics. The two common thermodynamic cycles used involve either the calculation of the free energy of sublimation (solid to gas without going through a liquid state) and the free energy of solvating a gaseous molecule (gas to solution), or the free energy of fusion (solid to a molten phase) and the free energy of mixing (molten to solution).
|
|
This signature sequence is highly conserved, with the exception that a valine residue in prokaryotic potassium channels is often substituted with an isoleucine residue in eukaryotic channels. This sequence adopts a unique main chain structure, structurally analogous to a nest protein structural motif. The four sets of electronegative carbonyl oxygen atoms are aligned toward the center of the filter pore and form a square anti-prism similar to a water-solvating shell around each potassium binding site. The distance between the carbonyl oxygens and potassium ions in the binding sites of the selectivity filter is the same as between water oxygens in the first hydration shell and a potassium ion in water solution, providing an energetically-favorable route for de-solvation of the ions.
|
|
They enter the negative electrode and flow through the external circuit to the positive electrode where a second double-layer with an equal number of anions has formed. The electrons reaching the positive electrode are not transferred to the anions forming the double-layer, instead they remain in the strongly ionized and "electron hungry" transition-metal ions of the electrode's surface. As such, the storage capacity of faradaic pseudocapacitance is limited by the finite quantity of reagent in the available surface. A faradaic pseudocapacitance only occurs together with a static double-layer capacitance, and its magnitude may exceed the value of double-layer capacitance for the same surface area by factor 100, depending on the nature and the structure of the electrode, because all the pseudocapacitance reactions take place only with de-solvated ions, which are much smaller than solvated ion with their solvating shell.
|
|