A historic championship drought will be quenched with a champagne shower.
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Our thirst for knowledge for more about the record's production will be quenched very soon.
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"There are just too many fires out there at the moment, which need to be quenched," he added.
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A person's thirst to control his or her own destiny will never be quenched by an angry tyrant or the secret police.
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Each time the water recedes, Hyder's characters are left parched with nostalgia, to be quenched only when the river is next in spate.
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Assume it knows where the water is, and you're just not peeking at it in a moment where its thirst needs to be quenched.
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A fire not to be quenched, it demands a uniform vigilance to prevent its bursting into a flame, lest, instead of warming, it should consume.
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Apart from the coolness factor, a truly solid phase of metallic hydrogen would be useful for all kinds of applications—assuming it could be "quenched to ambient pressure and temperature," Nellis told Gizmodo via email.
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By providing us with something of a blank screen through which we can draw whatever conclusions we so choose and see whatever influences we may see, she's igniting a curiosity that can't be quenched by anything other than our own brains.
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Singlet oxygen can be quenched by metal chelates, with nickel phenolates being a common example.
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It concludes (verse 31) with 'a reference to the burning of those who trust in their own strength', in a fire which cannot be 'quenched' (Heb. root: k-b-h), a relatively rare word which is also used in the last verse of the book (verse 66:24: 'their fire shall not be quenched'), thereby linking together beginning and ending of this whole book.
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The reaction can also be quenched with pyridine, which will scavenge ZnI2 and excess reagents.Denis, J. M.; Girard, C.; Conia, J. M. Improved Simmons-Smith Reactions. Synthesis 1972, 1972 (10), 549–551.
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Rome he described as "the pestilent hydra" and the pope "the sonne of sathan, and the manne of sinne, and the enimie unto the crosse of Christ, whose bloodthirstiness will never be quenched".
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Carbonitriding is similar to cyaniding except a gaseous atmosphere of ammonia and hydrocarbons is used instead of sodium cyanide. If the part is to be quenched, it is heated to ; if not, then the part is heated to .
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It is better for you to enter into life maimed, rather than having two hands, to go to hell, into the fire that shall never be quenched. And if your foot causes you to sin, cut it off.
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We can consider the possibility of a free sulfide, alkane thiol, or alkane persulfide being used as the sulfur donor for DTB. At physiological pH, these would all be protonated, and the carbon radical would likely be quenched by hydrogen atom transfer rather than by C-S bond formation.
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Some non- stilbene brighteners are used in more permanent applications such as whitening synthetic fiber. Brighteners can be "boosted" by the addition of certain polyols, such as high molecular weight polyethylene glycol or polyvinyl alcohol. These additives increase the visible blue light emissions significantly. Brighteners can also be "quenched".
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Additions involving higher-order cuprates must be quenched with a silyl halide before alkylation.F.-T. Luo, E. Negishi, J. Org. Chem. 1985, 50, 4762. (5)File:VDScope2.png When unsymmetrical cuprates are employed, the group whose carbon-copper bond contains less s character is almost always transferred to the β-position.
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Scheme 2. Heterolytic cleavage of polyethylene glycol. Polymers have also been observed to undergo heterolytic bond cleavage through isotope labeling experiments. When a bond is cleaved heterolytically, cationic and anionic species are formed that can in turn recombine to repair damage, can be quenched by solvent, or can react destructively with nearby polymers.
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Tellurium atoms form a distorted octahedron around the molybdenum atoms. This high-temperature form, termed β–MoTe2 can be quenched to room temperature by rapid cooling. In this metastable state β-MoTe2 can survive below 500 °C. When metastable β–MoTe2 is cooled below −20 °C, its crystal form changes to orthorhombic.
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After nucleophilic attack at boron, the resulting ketoboronate rearranges to a neutral enolborane. Upon protonolysis, a functionalized carbonyl compound results. The intermediate enolboranes may also be quenched with electrophiles. center Alkynylboronates are versatile intermediates that can be converted to either ketones or olefins after simultaneous migration and attack of the alkyne on a separate electrophile.
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EDANS (5-((2-Aminoethyl)amino)naphthalene-1-sulfonic acid) is a donor for FRET-based nucleic acid probes and protease substrates. EDANS is often paired with DABCYL or DABSYL. The combination can be used in enzyme assays. When the two compounds are in close proximity, most of the energy emitted from EDANS will be quenched by DABCYL.
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In these reactions, first syn-carboalumination takes place under the previously outlined mechanism. Then, another equivalent of aluminum that is coordinated to the directing group can displace the vinyl aluminum, inverting the geometry at the carbon where displacement takes place. Anti-Carboalumination of Alkynes (Negishi) This forms a thermodynamically favorable metallacycle to prevent subsequent inversions. Formally, this process provides anti-carboalumination products that can be quenched with electrophiles.
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Low viscosity permits rapid nucleation and ion migration, necessary for crystal formation. The high silica content of rhyolitic lavas gives them much higher viscosities. Such lavas tend to form glass (obsidian) when they cool rapidly from a fully melted liquid state; though many obsidians also contain microlites. Low viscosity mafic magmas must be quenched very rapidly from a high temperature to form glass that is free of any crystalline content.
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A classic example of this process is the quinine sulfate fluorescence, which can be quenched by the use of various halide salts. The excited molecule can de-excite by increasing the thermal energy of the surrounding solvated ions. Several natural molecules perform a fast internal conversion. This ability to transform the excitation energy of photon into heat can be a crucial property for photoprotection by molecules such as melanin.
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Mushet steel, also known as Robert Mushet's Special Steel (RMS) and, at the time of its use, self-hardening steel and air-hardening steel,. is considered to be both the first tool steel and the first air-hardening steel.. It was invented in 1868 by Robert Forester Mushet. Prior to Mushet steel, steel had to be quenched to harden it. It later led to the discovery of high speed steel.
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In 1868 English metallurgist Robert Forester Mushet developed Mushet steel, considered the forerunner of modern high-speed steels. It consisted of 2% carbon (C), 2.5% manganese (Mn), and 7% tungsten (W). The major advantage of this steel was that it hardened when air cooled from a temperature at which most steels had to be quenched for hardening. Over the next 30 years, the most significant change was the replacement of manganese (Mn) with chromium (Cr).
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The hydrogen gas produced intensifies the fire. Dry sand is an effective smothering agent, but only on relatively level and flat surfaces. Magnesium reacts with carbon dioxide exothermically to form magnesium oxide and carbon: :2 Mg + → 2 MgO + C (s) Hence, carbon dioxide fuels rather than extinguishes magnesium fires. Burning magnesium can be quenched by using a Class D dry chemical fire extinguisher, or by covering the fire with sand or magnesium foundry flux to remove its air source.
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The following month, Llagostera took control of the first urban enclosure, burning the city afterwards; a year later he managed to take it again, to abandon it soon after. In November 1836 he returned to seize the town, retaining it in his power for eleven days. And in June 1837, Carlist troops took Caspe but, before retiring, burned the town. According to official reports, 223 houses burned, and the fire could not be quenched until the next day.
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The exposed rock was then attacked by fire-setting where fires were used to heat the rock, which would be quenched with a stream of water. The thermal shock cracked the rock, enabling it to be removed. In some mines the Romans utilized water-powered machinery such as reverse overshot water-wheels. These were used extensively in the copper mines at Rio Tinto in Spain, where one sequence comprised 16 such wheels arranged in pairs, lifting water about .
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LED lamps of a specific wavelength are used to excite the pressure-sensitive probe within the paint. Once excited, the pressure-sensitive probe is transitioned to a higher energy state where is may either emit a photon or be quenched by local oxygen present. This competing process of emission and quenching determines the intensity response of the paint layer. The result is a dimmer fluorescence where there is higher pressure and brighter response at lower pressures.
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The implementation in a microscope is very similar to stimulated emission depletion microscopy, however it can operate with only one wavelength for excitation and depletion. Using an appropriate ring-like focal spot for the light that switches the molecules into the dark state, the fluorescence can be quenched at the outer part of the focal spot. Therefore, fluorescence only still takes place at the center of the microscope's focal spot and the spatial resolution is increased.
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In confinement, the range of composition of mixes of fuel and oxidant and self-decomposing substances with inerts are slightly below the flammability limits and for spherically expanding fronts well below them. The influence of increasing the concentration of diluent on expanding individual detonation cells has been elegantly demonstrated. Similarly their size grows as the initial pressure falls. Since cell widths must be matched with minimum dimension of containment, any wave overdriven by the initiator will be quenched.
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The disciples seem to think one needs to be part of Jesus' personal group but Jesus makes clear that anyone who works in his name and does his work is also for him. He then gives one of the most forceful condemnations of sin in the Bible (see Stumbling block): :And whosoever shall offend one of these little ones that believe in me, it is better for him that a millstone were hanged about his neck, and he were cast into the sea. And if thy hand offend thee, cut it off: it is better for thee to enter into life maimed, than having two hands to go into hell, into the fire that never shall be quenched: Where their worm dieth not, and the fire is not quenched. And if thy foot offend thee, cut it off: it is better for thee to enter halt into life, than having two feet to be cast into hell, into the fire that never shall be quenched: Where their worm dieth not, and the fire is not quenched.
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This allows for a wider range of metals that can be quenched and be given amorphous-like features instead of the general iron alloy. Another technique involves the consecutive spraying of the molten metal onto a chemical vapor deposition surface. However, the layers do not fuse together as desired and this causes oxides to be contained in the structure and pores to form around the structure. Manufacturing companies take an interest in the resultant products because of their near-net shaping capabilities.
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He was, however, readmitted and finished the teacher-training course in 1961. Subsequently, he took up a teaching position at the Tsumeb Primary School in Central Namibia, but soon discovered that his thirst for knowledge was unlikely to be quenched in Namibia. As a teacher, he also hated being an unwilling instrument in perpetuating the Bantu Education System. Therefore, at the end of the school year, he left his job to seek knowledge and instruction that could help him change the system.
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Monomers for living cationic polymerization are electron- rich alkenes such as vinyl ethers, isobutylene, styrene, and N-vinylcarbazole. The initiators are binary systems consisting of an electrophile and a Lewis acid. The method was developed around 1980 with contributions from Higashimura, Sawamoto and Kennedy. Typically, generating a stable carbocation for a prolonged period of time is difficult, due to the possibility for the cation to be quenched by a β-protons attached to another monomer in the backbone, or in a free monomer.
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The signal produced by a PID may be quenched when measuring in high humidity environments,Smith, P.A., Jackson Lepage, C., Harrer, K.L., and P.J. Brochu: Handheld photoionization instruments for quantitative detection of sarin vapor and for rapid qualitative screening of contaminated objects. J. Occ. Env. Hyg. 4:729-738 (2007). or when a compound such as methane is present in high concentrations of ≥1% by volumeNyquist, J.E., Wilson, D.L., Norman, L.A., and R.B. Gammage: Decreased sensitivity of photoionization detector total organic vapor detectors in the presence of methane.
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Consequently, the diameter of wholly sintered diamond blades is not very large, normally not more than . Because it is participating in the sintering process, the steel core cannot be quenched, so the hardness and strength of the core are not very high. This means that these types of diamond blade may deform in high-load and high-intensity cutting processes and can exhibit low cutting efficiency. Silver brazed and laser welded diamond blades do not have this weakness because their diamond segments and steel core are treated separately.
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Unlike shock compression, the pressure exerted is steady, and the sample can be heated using a furnace. Pressures of about 28 GPa (equivalent to depths of 840 km), and temperatures above 2300 °C, can be attained using WC anvils and a lanthanum chromite furnace. The apparatus is very bulky and cannot achieve pressures like those in the diamond anvil cell (below), but it can handle much larger samples that can be quenched and examined after the experiment. Recently, sintered diamond anvils have been developed for this type of press that can reach pressures of 90 GPa (2700 km depth).
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In Planitz, now a part of the city of Zwickau, a coal seam that had been burning since 1476 could only be quenched in 1860. In Dudweiler (Saarland) a coal seam fire ignited around 1668 and is still burning today. This so-called Burning Mountain ("Brennender Berg") soon became a tourist attraction and was even visited by Johann Wolfgang von Goethe. Also well-known is the so-called Stinksteinwand (stinking stone wall) in Schwalbenthal on the eastern slope of the Hoher Meißner, where several seams caught fire centuries ago after lignite coal mining ceased; combustion gas continues to reach the surface today.
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All performances came to a grinding halt during an 11-week impasse; at the end of the year the HSO finally negotiated new contracts where the work schedule became much more reasonable. The Hartford Symphony opened its doors once again on January 18, 1989. After that, it seemed that Hartford’s thirst for classical music could not be quenched. This year the Symphony started five new series: “Classical Conversations,” “Symphonikids” in-school concerts, Family concerts, a completely sold out series in local churches called “Music in a Gothic Space,” and a brand new set of summer concerts.
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In vitro, this enzyme exhibits promiscuous substrate specificity, also cyclizing 2,3-oxidosqualene. Aromatic residues in the active site form several unfavorable carbocations on the substrate which are quenched by a rapid polycyclization. In the last substep of the cyclization reaction, after electrons comprising the terminal alkene bond on the squalene have attacked the hopenyl carbocation to close the E ring, the C-22 carbocation may be quenched by mechanisms that lead to different hopanoid products. Nucleophilic attack of water will yield diplopterol, while deprotonation at an adjacent carbon will form one of several hopene isomers, often diploptene.
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The steel core can be quenched and processed with other heat treatments, so its hardness and strength can be high, meaning that the blade can be used in high-load and high-intensity cutting processes with high cutting efficiency and a smaller degree of deformation. Silver brazed diamond blades' diamond segments are brazed to the steel core using a silver solder. These blades can only be used in wet cuttings. If they are used in dry cuttings, the silver solder may melt and the segments can break from the steel core and become a serious safety hazard.
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The rock was then worked upon by fire-setting to heat the rock, which would be quenched with a stream of water. The resulting thermal shock cracked the rock, enabling it to be removed by further streams of water from the overhead tanks. The Roman miners used similar methods to work cassiterite deposits in Cornwall and lead ore in the Pennines. The methods had been developed by the Romans in Spain in 25 AD to exploit large alluvial gold deposits, the largest site being at Las Medulas, where seven long aqueducts tapped local rivers and sluiced the deposits.
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That spreading ridges could be subducted was recognized early in the development of plate tectonic theory, but there was little consideration of the ensuing effects. In the 1980s came realization that the magma welling up from the asthenosphere through the subducted ridge would not reach seawater, and thus not be quenched to form rock and close the gap. Continued spreading would lead to a widening gap or "window" in the subducting plate through which there could be increased flow of magma.. The implications of this for Siletzia were first shown by and (following the pioneering work by ).; .
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London, 1919. pp 82-83 and 163 In relation to the contemplative life, he held that three attributes should be acquired: The first is spiritual freedom from worldly desires ("as empty of every outward work as if he did not work at all"), the second is a mind unencumbered with images ("inward silence"), and the third is a feeling of inward union with God ("even as a burning and glowing fire which can never more be quenched").The Adornment of the Spiritual Marriage; The Sparkling Stone; The Book of the Supreme Truth. Translation by C. A. Wynschenk.
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The king demanded to know who had loosed the bull so that he may be executed, but when Andriamampandry took responsibility he warned the king that yet more blood would be spilled before the earth would be quenched. He then criticized the king for his concern over the relatively few deaths at the gathering, in light of the number of people who would die as a consequence of his division of Imerina. He further predicted that the prince at Ambohimanga would unite Imerina and lead it back to greatness. Andriamasinavalona reportedly had no response to give Andriamampandry, but instead hung his head in shame.
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If made from carbon nanotubes or graphene (a sheet-like carbon allotrope), then the major structural materials can be produced using carbon dioxide gathered in situ from the atmosphere. The recently synthesised amorphous carbonia might prove a useful structural material if it can be quenched to Standard Temperature and Pressure (STP) conditions, perhaps in a mixture with regular silica glass. According to Birch's analysis, such colonies and materials would provide an immediate economic return from colonizing Venus, funding further terraforming efforts. Increasing the planet's albedo by deploying light-colored or reflective material on the surface (or at any level below the cloud tops) would not be useful, because the Venerian surface is already completely enshrouded by clouds, and almost no sunlight reaches the surface.
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Moreover, and variety of aryl halides are well tolerated as coupling partners including those bearing both electron-withdrawing and electron- donating groups, as well as π-rich and π-deficient aromatic heterocyclic compounds. Stereochemistry is an important element to consider when preparing polysubstituted olefins. Using hydrazones derived from linear aldehydes resulted in exclusively trans olefins, while the stereochemical outcomes of trisubstituted olefins were dependent on the size of the substituents. center The mechanism of this transformation is thought to proceed in a manner similar to the synthesis of alkenes through the Bamford–Stevens reaction; the decomposition of N-tosylhydrazones in the presence of base to generate diazocompounds which then release nitrogen gas, yielding a carbene, which then can be quenched with an electrophile.
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In the 1590s, Molyneux sought Elizabeth I's patronage for the production of a cannon, which he described as his "new invention, of shot and artillery, to be used principally in naval warfare: protection of ports and harbours, a new shot to discharge a thousand musket shot; with wildfire not to be quenched".Calendar of State Papers: Domestic Series, 1574–1580; 1595–1597. In March 1593, Molyneux was issued with a royal warrant. Two years later, the merchant Robert Parkes purchased coal, saltpetre, pitch, oils and waxes for him, possibly for the cannon. On 4 November 1596 the Privy Council urged the Lord Admiral "to speak to Molyneux, Bussy and the two Engelberts about their offensive engines"Calendar of State Papers: Domestic Series, 1595–1597, p. 303.
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Let not your lamps be quenched, nor your loins > unloosed; but be ready, for you know not the hour in which our Lord comes. > But often shall you come together, seeking the things which are befitting to > your souls: for the whole time of your faith will not profit you, if you be > not made perfect in the last time. For in the last days false prophets and > corrupters shall be multiplied, and the sheep shall be turned into wolves, > and love shall be turned into hate; for when lawlessness increases, they > shall hate and persecute and betray one another, and then shall appear the > world-deceiver as the Son of God, and shall do signs and wonders, and the > earth shall be delivered into his hands, and he shall do iniquitous things > which have never yet come to pass since the beginning.
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Tetracalcium phosphate cannot be prepared in aqueous solution, any precipitates having the correct Ca/P ratio contain hydroxide ions in apatitic phases. Solid state reactions are used, one example is: :2 CaHPO4 \+ 2 CaCO3 → Ca4(PO4)2O + CO2 \+ H2O (1450-1500 °C for up to 12 hours) As tetracalcium phosphate is metastable the molten reaction mixture has to be quenched to rapidly, reduce the temperature and prevent the formation of other compounds such as Ca3(PO4)2, CaO, CaCO3 and Ca5(PO4)3(OH). Unwanted tetracalcium phosphate can be formed when metal alloy implants (orthopaedic and dental) are plasma spayed with hydroxyapatite. Tetracalcium phosphate is stable in water at room temperature for up to four weeks, but at higher temperatures hydrolyses to hydroxyapatite and calcium hydroxide: :3 Ca4(PO4)2O + 3 H2O → 2 Ca5(PO4)3(OH) + 2 Ca(OH)2 Tetracalcium phosphate is a component used in the formation of some hydroxyapatite calcium phosphate cements that used for the repair of bone defects.
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